S. Sreekumar, H. Pacheco, D. O’Carroll
Rutgers University,
United States
Keywords: light-emitting devices, transparent electrodes, plasmonic metasurfaces
Summary:
Alternative transparent conducting electrodes (TCEs) have gained significant attention in recent decades in an effort to replace costly indium-tin oxide (ITO) in organic optoelectronic devices. For example, state-of-the-art top-emitting, transparent organic light-emitting diodes (OLEDs) in the display industry require a transparent or semi-transparent cathode for electron injection. The current OLED display technology employs ultrathin metallic (typically Mg:Ag) layers as semitransparent cathodes. However, recent studies have shown that metal oxide/metal/meta-oxide multiplayers can perform better optically and offer improved stability compared to semitransparent metal cathodes. Yet, deposition of these multilayers with minimal damage to the underlying organic emissive layer is imperative. Here, we investigate the ZnO/Ag/ZnO TCE system deposited under mild sputtering conditions that are safe for the emissive layer. We demonstrate ~85% transparent electrodes with a sheet resistance of 1.47 /□, which is more conductive than the industry standard, ITO. We also integrated such a multilayer electrode in a transparent OLED device built on ITO, demonstrating the compatibility of this TCE with the existing OLED technology. In addition to the multilayer TCE, we demonstrate proof-of-concept research that integrates plasmonic particles and metasurfaces into bottom- and top-emitting blue OLEDs to boost their efficiency and operational lifetime.